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Tokyo Chemical Industry 2,2′-bis(trifluoromethyl)benzidine tfb
2,2′ Bis(trifluoromethyl)benzidine Tfb, supplied by Tokyo Chemical Industry, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/bis(trifluoromethyl)benzidine/2+2++bis+trifluoromethyl+benzidine++tfmb+/pm40162693-247-0-7
Average 90 stars, based on 1 article reviews
2,2′-bis(trifluoromethyl)benzidine tfb - by Bioz Stars, 2026-09
90/100 stars

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Article Title: Graphene Nanofibers by Integrated Manufacturing of Electrospinning and Laser Graphitization for Miniaturized Energy Storage Devices.
Article Snippet: 2,2′-Bis(trifluoromethyl)benzidine (TFB; C14H10F6N2, >98.0%) was obtained from TCI chemicals (Japan).

Article Title: Graphene Nanofibers by Integrated Manufacturing of Electrospinning and Laser Graphitization for Miniaturized Energy Storage Devices
Article Snippet: 2,2′‐Bis(trifluoromethyl)benzidine (TFB; C 14 H 10 F 6 N 2 , >98.0%) was obtained from TCI chemicals (Japan).

Purification:

Article Title: Curing Kinetics of Ultrahigh-Temperature Thermosetting Polyimides Based on Phenylethynyl-Terminated Imide Oligomers with Different Backbone Conformations
Article Snippet: A series of phenylethynyl-terminated imide (PETI) oligomers with varying chemical backbones and calculated number-average molecular weights were successfully synthesized via chemical imidization.. These PETI oligomers exhibited exceptional solubility (>50 wt %) in both the high-boiling-point solvent N-methyl-2-pyrrolidinone (NMP) and low-boiling-point solvents tetrahydrofuran (THF) and 1,4-dioxane (dioxane).. The curing reactivities of the PETI oligomers were assessed based on the dianhydride structure using a nonisothermal differential scanning calorimetry (DSC) method.

Article Title: Transparent Poly(amide-imide)s with Low Coefficient of Thermal Expansion from Trifluoromethylated Trimellitic Anhydride.
Article Snippet: 5-Bromo-1,2,4-trimethylbenzene (Alfa Aesar, Ward Hill, MA, USA, 99%), sodium hydroxide (NaOH, Daejung, 99%), potassium permanganate (KMnO4, Aldrich, Saint Louis, MO, USA, 99%), methanol (Daejung, Seoul, Republic of Korea, 99.8%), methyldifluoro(fluorosulfonyl)acetate (FSO2CF2COOMe, TCI, Tokyo, Japan, 97%), tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd2(dba)3-CHCl3, Aldrich, 98%), triphenylarsine (Aldrich, 97%), copper (I) iodide (Aldrich, 99.5%), 1,4-diazabicyclo [2.2.2]octane (DABCO, Aldrich, 99%), 4-aminobenzoic acid (Aldrich, 99%), 3-aminobenzotrifluoride (TCI, 99%), p-anisidine (Aldrich, 99%), anhydrous 1,4-dioxane (Aldrich, Saint Louis, MO, USA, 99.8%), acetic anhydride (Aldrich, Saint Louis, MO, USA, 99.5%), anhydrous N,N-dimethylformamide (DMF, Aldrich, Saint Louis, MO, USA, 99.8%), anhydrous N,Ndimethylacetamide (DMAc, Aldrich, Saint Louis, MO, USA, 99.8%), anhydrous N-methyl2-pyrrolidone (NMP, Aldrich, Saint Louis, MO, USA, 99.5%), anhydrous pyridine (Aldrich, Polymers 2025, 17, 309 3 of 20 Saint Louis, MO, USA, 99.8%), and triphenyl phosphite (TCI, Tokyo, Japan, 97%) were purchased from commercial vendors and used as received. .. 2,2′-Bis(trifluoromethyl)benzidine (sDA) was purchased from TCI and purified by vacuum sublimation at 120 ◦C. .. Terephthalic acid (TA) was purchased from TCI and purified by vacuum sublimation at 210 ◦C.

Article Title: Transparent Poly(amide-imide)s with Low Coefficient of Thermal Expansion from Trifluoromethylated Trimellitic Anhydride
Article Snippet: 5-Bromo-1,2,4-trimethylbenzene (Alfa Aesar, Ward Hill, MA, USA, 99%), sodium hydroxide (NaOH, Daejung, 99%), potassium permanganate (KMnO 4 , Aldrich, Saint Louis, MO, USA, 99%), methanol (Daejung, Seoul, Republic of Korea, 99.8%), methyldifluoro(fluorosulfonyl)acetate (FSO 2 CF 2 COOMe, TCI, Tokyo, Japan, 97%), tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd 2 (dba) 3 -CHCl 3 , Aldrich, 98%), triphenylarsine (Aldrich, 97%), copper (I) iodide (Aldrich, 99.5%), 1,4-diazabicyclo [2.2.2]octane (DABCO, Aldrich, 99%), 4-aminobenzoic acid (Aldrich, 99%), 3-aminobenzotrifluoride (TCI, 99%), p -anisidine (Aldrich, 99%), anhydrous 1,4-dioxane (Aldrich, Saint Louis, MO, USA, 99.8%), acetic anhydride (Aldrich, Saint Louis, MO, USA, 99.5%), anhydrous N,N-dimethylformamide (DMF, Aldrich, Saint Louis, MO, USA, 99.8%), anhydrous N,N-dimethylacetamide (DMAc, Aldrich, Saint Louis, MO, USA, 99.8%), anhydrous N-methyl-2-pyrrolidone (NMP, Aldrich, Saint Louis, MO, USA, 99.5%), anhydrous pyridine (Aldrich, Saint Louis, MO, USA, 99.8%), and triphenyl phosphite (TCI, Tokyo, Japan, 97%) were purchased from commercial vendors and used as received. .. 2,2′-Bis(trifluoromethyl)benzidine ( s DA ) was purchased from TCI and purified by vacuum sublimation at 120 °C. .. Terephthalic acid ( TA ) was purchased from TCI and purified by vacuum sublimation at 210 °C.

Sublimation:

Article Title: Transparent Poly(amide-imide)s with Low Coefficient of Thermal Expansion from Trifluoromethylated Trimellitic Anhydride.
Article Snippet: 5-Bromo-1,2,4-trimethylbenzene (Alfa Aesar, Ward Hill, MA, USA, 99%), sodium hydroxide (NaOH, Daejung, 99%), potassium permanganate (KMnO4, Aldrich, Saint Louis, MO, USA, 99%), methanol (Daejung, Seoul, Republic of Korea, 99.8%), methyldifluoro(fluorosulfonyl)acetate (FSO2CF2COOMe, TCI, Tokyo, Japan, 97%), tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd2(dba)3-CHCl3, Aldrich, 98%), triphenylarsine (Aldrich, 97%), copper (I) iodide (Aldrich, 99.5%), 1,4-diazabicyclo [2.2.2]octane (DABCO, Aldrich, 99%), 4-aminobenzoic acid (Aldrich, 99%), 3-aminobenzotrifluoride (TCI, 99%), p-anisidine (Aldrich, 99%), anhydrous 1,4-dioxane (Aldrich, Saint Louis, MO, USA, 99.8%), acetic anhydride (Aldrich, Saint Louis, MO, USA, 99.5%), anhydrous N,N-dimethylformamide (DMF, Aldrich, Saint Louis, MO, USA, 99.8%), anhydrous N,Ndimethylacetamide (DMAc, Aldrich, Saint Louis, MO, USA, 99.8%), anhydrous N-methyl2-pyrrolidone (NMP, Aldrich, Saint Louis, MO, USA, 99.5%), anhydrous pyridine (Aldrich, Polymers 2025, 17, 309 3 of 20 Saint Louis, MO, USA, 99.8%), and triphenyl phosphite (TCI, Tokyo, Japan, 97%) were purchased from commercial vendors and used as received. .. 2,2′-Bis(trifluoromethyl)benzidine (sDA) was purchased from TCI and purified by vacuum sublimation at 120 ◦C. .. Terephthalic acid (TA) was purchased from TCI and purified by vacuum sublimation at 210 ◦C.

Article Title: Transparent Poly(amide-imide)s with Low Coefficient of Thermal Expansion from Trifluoromethylated Trimellitic Anhydride
Article Snippet: 5-Bromo-1,2,4-trimethylbenzene (Alfa Aesar, Ward Hill, MA, USA, 99%), sodium hydroxide (NaOH, Daejung, 99%), potassium permanganate (KMnO 4 , Aldrich, Saint Louis, MO, USA, 99%), methanol (Daejung, Seoul, Republic of Korea, 99.8%), methyldifluoro(fluorosulfonyl)acetate (FSO 2 CF 2 COOMe, TCI, Tokyo, Japan, 97%), tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd 2 (dba) 3 -CHCl 3 , Aldrich, 98%), triphenylarsine (Aldrich, 97%), copper (I) iodide (Aldrich, 99.5%), 1,4-diazabicyclo [2.2.2]octane (DABCO, Aldrich, 99%), 4-aminobenzoic acid (Aldrich, 99%), 3-aminobenzotrifluoride (TCI, 99%), p -anisidine (Aldrich, 99%), anhydrous 1,4-dioxane (Aldrich, Saint Louis, MO, USA, 99.8%), acetic anhydride (Aldrich, Saint Louis, MO, USA, 99.5%), anhydrous N,N-dimethylformamide (DMF, Aldrich, Saint Louis, MO, USA, 99.8%), anhydrous N,N-dimethylacetamide (DMAc, Aldrich, Saint Louis, MO, USA, 99.8%), anhydrous N-methyl-2-pyrrolidone (NMP, Aldrich, Saint Louis, MO, USA, 99.5%), anhydrous pyridine (Aldrich, Saint Louis, MO, USA, 99.8%), and triphenyl phosphite (TCI, Tokyo, Japan, 97%) were purchased from commercial vendors and used as received. .. 2,2′-Bis(trifluoromethyl)benzidine ( s DA ) was purchased from TCI and purified by vacuum sublimation at 120 °C. .. Terephthalic acid ( TA ) was purchased from TCI and purified by vacuum sublimation at 210 °C.



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